What is Vanadium Dioxide?

Vanadium Dioxide

Vanadium Dioxide (VO2) is a thermochromic phase-transition oxide candidate for Smart Glazing and thermally responsive IR-control coatings.

Technical owner: Aurexene Materials Engineering Team · Last updated: 2026-06-18

VO2vanadium(IV) oxide

Quick Answer

Vanadium Dioxide (VO2) is the thermochromic smart-glazing route in this material set. Its temperature-dependent phase transition, transition temperature, hysteresis, optical modulation, and switching durability require final-stack validation.

What It Is Not

  • Vanadium Dioxide is VO2, not V2O3, V2O5, or V4O7; oxidation state and phase are part of its switching identity.

When Not to Use It

  • Do not use VO2 when only static NIR attenuation is required and thermochromic transition behavior, hysteresis, or switching durability cannot be managed.

Intrinsic Screening Summary

Identity screen
VO2; Vanadium dioxide phase-transition oxide particles

Application Fit

Material Identity & Specification Status

Approved values for Particle size, Purity, and Packaging are not published; confirm them during quotation or sample review.

PropertyValue
CompositionVO2
CAS / identity12036-21-4
MorphologyVanadium dioxide phase-transition oxide particles
Density4.57 g/cm3 intrinsic VO2 density
StorageDry sealed container

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Technical Guides

Technical GuideSummary
Balancing Film Thickness, Visible Transmission, Solar Modulation, Color, and DurabilityBalancing Film Thickness, Visible Transmission, Solar Modulation, Color, and Durability — a method-conditioned engineering guide for Smart Glazing covering structure-function behavior at the material, interface, and finished-system boundary, process limits, validation, and qualification boundaries.
Diagnosing Weak Switching, Broad Transitions, and Excessive HysteresisDiagnosing Weak Switching, Broad Transitions, and Excessive Hysteresis — a method-conditioned engineering guide for Smart Glazing covering structure-function behavior at the material, interface, and finished-system boundary, process limits, validation, and qualification boundaries.
Dispersing Thermochromic Particles Without Suppressing Switching or Increasing HazeDispersing Thermochromic Particles Without Suppressing Switching or Increasing Haze — a method-conditioned engineering guide for Smart Glazing covering structure-function behavior at the material, interface, and finished-system boundary, process limits, validation, and qualification boundaries.
How Doping, Defects, and Stoichiometry Change VO2 Switching BehaviorHow Doping, Defects, and Stoichiometry Change VO2 Switching Behavior — a method-conditioned engineering guide for Smart Glazing covering structure-function behavior at the material, interface, and finished-system boundary, process limits, validation, and qualification boundaries.
How Particle Size, Phase Purity, and Crystallinity Affect Thermochromic CoatingsHow Particle Size, Phase Purity, and Crystallinity Affect Thermochromic Coatings — a method-conditioned engineering guide for Smart Glazing covering structure-function behavior at the material, interface, and finished-system boundary, process limits, validation, and qualification boundaries.

Documents & Inquiry

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Grade, Sample & Qualification Support

The Aurexene Materials Engineering Team can review the required form, host system, formulation or process, target, sample quantity, volume and timeline, and the grade-specific evidence needed before qualification.

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