What is Hydrophobic Fumed Silica?

Hydrophobic Fumed Silica (HFS)

Aurexene Materials Hydrophobic Fumed Silica is an 11-grade family of surface-treated synthetic amorphous silica powders for rheology, suspension, anti-sag, reinforcement, and powder-flow control.

Technical owner: Aurexene Materials Engineering Team · Last updated: 2026-08-10

HFShydrophobic silicatreated fumed silicasurface-treated synthetic amorphous silicaanti-sag silica

Quick Answer

Aurexene Materials Hydrophobic Fumed Silica is a surface-treated fumed-silica grade family used to build low-shear structure, improve suspension and anti-sag behavior, reinforce silicone elastomers, and support powder-flow and caking control.

What It Is Not

  • Hydrophobic fumed silica is a formulation additive, not a finished adhesive, sealant, coating, ink, elastomer, thermal interface material, or powder blend.
  • The grade-family screening ranges below are not guaranteed release specifications; confirm the current grade TDS, COA, test method, and lot before qualification.

When Not to Use It

  • Do not select a grade when its surface treatment, residual profile, dust controls, matrix compatibility, or current safety documentation cannot be confirmed for the intended process and market.

Intrinsic Screening Summary

Identity screen
Synthetic amorphous silica base with a hydrophobic surface treatment; the family includes PDMS-, DDS-, HMDS-, and D4-treated grades plus two grades whose treatment is not specified in the controlled family data.; Surface-treated fumed-silica powder; exact primary-particle and agglomerate morphology are not specified in the controlled family data.
Intrinsic feature
Dispersed particles can form a reversible network whose low-shear structure and recovery depend on surface area, treatment, matrix polarity, loading, dispersion energy, and shear history.
Material-level integration
Screen surface treatment, BET area, carbon, pH, and tapped density together.

Application Fit

ApplicationSuitabilityConditionsLimitations
Rheology, Suspension & Anti-Sag ControlGOOD FITScreen for silicone elastomers, adhesives and sealants, coatings and inks, and dry powder systems where low-shear structure, suspension, anti-sag, reinforcement, flow, or caking control is required.Select and qualify the exact surface treatment, BET range, loading, dispersion process, rheology method, and storage response in the final formulation.
Thermally Conductive & Electrically Insulating PolymersCONDITIONALDevelopmental rheology and storage-stability aid in silicone formulations containing BN, AlN, or Al2O3 thermal fillers.No component-level thermal performance or universal loading is supplied; qualify dispensing force, voiding, thermal response, cure, and storage uniformity in the final compound.
Electronic Packaging & InterconnectsCONDITIONALDevelopmental rheology and filler-suspension aid in resin or silicone encapsulation systems.Qualify voids, cure, moisture behavior, electrical properties, contamination controls, reliability cycling, and the exact grade residual profile before package use.

Selection & Validation Framework

Decision QuestionMaterial-Level Answer
Addition order and dispersionEstablish addition order, dispersion energy, and shear history in a controlled formulation trial. Use the actual silicone, resin, adhesive, coating, ink, or powder system; no grade-specific protocol is supplied.
LoadingSet loading experimentally on a stated weight or volume basis. No validated universal loading range is supplied; stop when rheology, dispersion, processability, cure, or final performance leaves acceptance.
Process controlsValidate temperature, atmosphere, pH, viscosity, filtration, dust controls, and equipment response in the actual process.
Rheology, sag, and suspensionRequired for: Rheology, Suspension & Anti-Sag Control. Measure: viscosity across the relevant shear-rate range; yield or low-shear structure by the selected method; recovery after shear; sag and leveling; settling and storage stability. Sample state: Final formulation after defined mixing, deaeration, conditioning, and aging. Failure signals: Structure is too weak to prevent sag or settling.; Structure is too strong for leveling, pumping, dispensing, or mixing..

Material Identity & Specification Status

Approved values for Packaging are not published; confirm them during quotation or sample review.

PropertyValueMethodCondition
CompositionSynthetic amorphous silica base with a hydrophobic surface treatment; the family includes PDMS-, DDS-, HMDS-, and D4-treated grades plus two grades whose treatment is not specified in the controlled family data.
CAS / identity112945-52-5 (generic base-silica reference; confirm exact identifiers by grade)
Particle sizePrimary-particle size, agglomerate-size distribution, and D-values are not specified in the family TDS; request current grade data.
MorphologySurface-treated fumed-silica powder; exact primary-particle and agglomerate morphology are not specified in the controlled family data.
DensityBulk density (tapped) is approximately 60 g/L for ten grades and 100 to 220 g/L for HD2000G; confirm the current grade method and release data.
PuritySilica purity, crystalline-silica impurity basis, treatment concentration, and residual content are not specified in the family TDS.
StorageKeep dry, closed, and protected from moisture and contamination; exact temperature, humidity, and shelf-life limits require current grade documentation.
Product family codeAUX-HFS-FAMILYDocument identity
Grade family11 gradesFamily lineup
CAS Number112945-52-5 (generic base-silica reference)Family document reference
BET surface area80–260 m²/g across the familyConfirm current grade methodFamily formulation-selection ranges, not release specifications
Tapped densityApproximately 60 g/L for HD171 through HD805; 100–220 g/L for HD2000GConfirm current grade methodFamily formulation-selection ranges, not release specifications

Functional Performance

PropertyValueConditions
Rheology and thixotropic recoveryFormulation-dependent; no universal viscosity or yield-value target is claimed.Measure the full shear-rate profile, low-shear recovery, temperature response, and aging in the final matrix. Surface area alone does not predict finished-formulation rheology.
Suspension and anti-sag controlFormulation-dependent; qualify settling, sag, leveling, and dispense behavior together.Use the final resin, pigment or filler package, loading, dispersion energy, and shear history. Excess structure can impair leveling, pumping, dispensing, mixing, or degassing.
Powder flow and caking controlPowder-system dependent; no universal dose or flow index is claimed.Qualify dustiness, humidity, dosage, blend uniformity, storage, and downstream processing. A flow aid cannot compensate for uncontrolled moisture, segregation, or an incompatible blending process.

Why It Works

StructureFunctionMechanism
Hydrophobically surface-treated fumed-silica particle networkLow-shear structure, recovery, suspension, anti-sag behavior, reinforcement, and powder-flow control in compatible formulations.Dispersed particles can form a reversible network whose low-shear structure and recovery depend on surface area, treatment, matrix polarity, loading, dispersion energy, and shear history.

Compare Material Routes

Material / RouteDecision Boundary
PDMS-, DDS-, HMDS-, and D4-treated HFS gradesMultiple treatment and surface-area families allow compatibility and rheology screens across organic matrices. Treatment name, BET area, carbon, pH, and tapped density are screening variables; final performance and residual requirements must be qualified by grade.

Failure-Mode Watchouts

Failure ModeTriggerMaterial-Level Response
Sag or settling remains uncontrolledInsufficient structure, incompatible treatment, low effective loading, or a dispersion process that does not build the required network.Re-screen grade treatment and BET family, then re-optimize loading, addition order, dispersion energy, and conditioning in the final matrix.
The formulation becomes difficult to mix, level, pump, dispense, filter, or degas.Excess structure, unsuitable surface treatment, excessive loading, agglomeration, or unrepresentative shear history.Reduce or change the HFS route and qualify the full rheology curve, process torque, filtration or nozzle response, and air release.
Viscosity, suspension, or powder flow drifts during storage.Moisture, incomplete dispersion, matrix incompatibility, changing shear history, or uncontrolled conditioning.Control storage, moisture, mixing history, and aging protocol; compare initial and aged acceptance in the final package.

Technical Guides

Technical GuideSummary
Managing High Filler Loading, Viscosity, Mixing Torque, and MoldabilityManaging High Filler Loading, Viscosity, Mixing Torque, and Moldability — a method-conditioned engineering guide for Thermally Conductive & Electrically Insulating Polymers covering structure-function behavior at the material, interface, and finished-system boundary, process limits, validation, and qualification boundaries.

FAQ

How should the 11 HFS grades be compared?

Start with surface treatment, BET surface area, carbon, pH, and tapped density, then qualify the exact grade in the final matrix with controlled loading, dispersion, shear history, and aging.

Is Hydrophobic Fumed Silica a thermal filler?

It is not presented here as the primary heat-conducting filler. In thermal formulations it is a developmental rheology and suspension aid that must be tested with the actual BN, AlN, or Al2O3 filler package.

Commercial Availability

Supplier role: Request confirmation

Supply status: Request confirmation

Sample status: Sample availability requires confirmation

Commercial details are not published until the source and verification fields are complete and the Supplier Data Packet is signed by the sales owner, technical reviewer, and resource/compliance owner. Request current grade, form, sample, packaging, and delivery confirmation.

Documents & Inquiry

Document access follows the current approval state. Unapproved or unavailable files route to a document request instead of a public download.

Grade, Sample & Qualification Support

Aurexene Materials helps shortlist HFS grades by matrix, treatment family, surface area, rheology target, sag or settling risk, process window, storage condition, dust controls, and documentation needs.

Hydrophobic Fumed Silica RFQ qualification checklist

  • Matrix chemistry, cure route, fillers or pigments, and supplied form:
  • Target rheology curve, sag, settling, recovery, leveling, or powder-flow response:
  • Mixing, dispersion, addition order, temperature, shear history, filtration, and dispensing process:
  • Loading basis, batch size, storage condition, aging time, and package format:
  • Required treatment disclosure, residual limits, current TDS, SDS, COA, and market classification:

This inquiry and qualification path does not guarantee performance or availability:

  1. Define the matrix, application subtype, rheology or powder-flow objective, and process acceptance window.
  2. Screen treatment family, BET range, carbon, pH, and tapped density without treating family ranges as release specifications.
  3. Compare shortlisted grades in the final formulation using controlled addition, dispersion, conditioning, and aging.
  4. Confirm the current grade TDS, SDS, COA, treatment, residual profile, dust controls, and regulatory fit before release.

The family TDS supports formulation screening, not a guaranteed grade specification or finished-system performance claim. Final recommendations require current grade documents and application-level validation.

Review Lab Capabilities for sample evaluation and qualification support, or Production Capabilities for scale-up, quality, documentation, and supply support.

Request Hydrophobic Fumed Silica Sample / Qualification Review